Nitration is a post-translational modification of mostly tyrosine residues that is caused by oxidation. First, a tyrosine radical is formed by one-electron oxidation followed by a reaction with nitrogen dioxide resulting in 3-nitrotyrosine. Lit.
|
λ / nm |
ε / M-1 cm-1 |
|---|---|
| 214 | 0 |
| 240 | 0 |
| 245 | 0 |
| 250 | 2267 |
| 255 | 2646 |
| 260 | 3308 |
| 265 | 3783 |
| 270 | 4279 |
| 272 | 4321 |
| 274 | 4388 |
| 276 | 4521 |
| 278 | 4588 |
| 280 | 4563 |
| 282 | 4521 |
| 284 | 4642 |
| 286 | 4750 |
| 288 | 4608 |
| 290 | 4421 |
| 292 | 4225 |
| 294 | 3867 |
| 296 | 3496 |
| 298 | 3088 |
| 300 | 2833 |
| 302 | 2583 |
| 304 | 2383 |
| 306 | 2175 |
| 308 | 1921 |
| 310 | 1813 |
| 312 | 1725 |
| 314 | 1658 |
| 316 | 1650 |
| 318 | 1658 |
| 320 | 1679 |